I think they should start blocking somewhere around 1600 accuracy ability. Although, I can't remember for sure, but I know this is true for UK gunners so the stats may be off as its been a long time since I leveled KM gunners. However, with good base stats, boosts, and vets they can easily block before they're capped out of Blitz rooms. Therefore I'd venture to guess anywhere from level 55-60. Maybe a little earlier if you're lucky.
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